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绿色化工 5

膜分离 5

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uncoupler, 3,3′,4′,5-tetrachlorosalicylanilide addition for sludge reduction and fouling control in a gravity-drivenmembrane bioreactor

An Ding, Yingxue Zhao, Huu Hao Ngo, Langming Bai, Guibai Li, Heng Liang, Nanqi Ren, Jun Nan

《环境科学与工程前沿(英文)》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1275-4

摘要: Abstract • Effects of metabolic uncoupler TCS on the performances of GDMBR were evaluated. • Sludge EPS reduced and transformed into dissolved SMP when TCS was added. • Appropriate TCS increased the permeability and reduced cake layer fouling. • High dosage aggravated fouling due to compact cake layer with low bio-activity. The gravity-driven membrane bioreactor (MBR)system is promising for decentralized sewage treatment because of its low energy consumption and maintenance requirements. However, the growing sludge not only increases membrane fouling, but also augments operational complexities (sludge discharge). We added the metabolic uncoupler 3,3′,4′,5-tetrachlorosalicylanilide (TCS) to the system to deal with the mentioned issues. Based on the results, TCS addition effectively decreased sludge ATP and sludge yield (reduced by 50%). Extracellular polymeric substances (EPS; proteins and polysaccharides) decreased with the addition of TCS and were transformed into dissolved soluble microbial products (SMPs) in the bulk solution, leading to the break of sludge flocs into small fragments. Permeability was increased by more than two times, reaching 60–70 L/m2/h bar when 10–30 mg/L TCS were added, because of the reduced suspended sludge and the formation of a thin cake layer with low EPS levels. Resistance analyses confirmed that appropriate dosages of TCS primarily decreased the cake layer and hydraulically reversible resistances. Permeability decreased at high dosage (50 mg/L) due to the release of excess sludge fragments and SMP into the supernatant, with a thin but more compact fouling layer with low bioactivity developing on the membrane surface, causing higher cake layer and pore blocking resistances. Our study provides a fundamental understanding of how a metabolic uncoupler affects the sludge and bio-fouling layers at different dosages, with practical relevance for in situ sludge reduction and membrane fouling alleviation in MBR systems.

关键词: Gravity-driven membrane (GDM)     Energy uncoupling     Permeability     Sludge reduction     Membrane fouling     Fouling layer    

Dynamic analysis of free-surface thin film flows driven by gravity over undulated substrate

Zhaomiao LIU, Xin LIU, Guobin WANG, Hong LIAO,

《机械工程前沿(英文)》 2010年 第5卷 第2期   页码 219-225 doi: 10.1007/s11465-010-0010-4

摘要: This paper studies thin film flows with free surfaces driven by gravity through two types of undulated planes: periodically sinusoidal plane and triangle. The substrate plane is fixed and inclined to a certain angle and the flow with a free surface. Through finite element method (FEM), commenced from Navier-Stokes equations and continuity equation, the exact numerical results of free-surface film flows are obtained through discretization solution to finite equations in flowing areas. Based on the numerical calculations, the streamlines and wall shearing stress during the flowing process are visualized via post-proceeding, and the streamlines separation, the onset and evolution of vortex near the substrate boundary during the flow are also analyzed. The influences from the waviness of the substrate planes profile, height of the triangle plane, and change of the film height on film flow dynamics properties are shown.

关键词: waviness     triangle height     film thickness     streamlines separation     vortex    

氯化水与地表水导致的膜污染对比解析——生物污染特性和微生物探究 Article

张莉, 徐磊, Nigel Graham, 俞文正

《工程(英文)》 2022年 第15卷 第8期   页码 154-164 doi: 10.1016/j.eng.2021.03.016

摘要:

氯在城市水处理过程中通常用于灭活病原体和预防水媒疾病,但是目前尚不清楚其作为一种预处理技术是否能够有效地缓解超滤过程中产生的膜污染。在本研究中,我们探究了自来水在重力驱动膜过滤系统中对生物膜的形成及生物污染的影响。同时,未处理的地表水(湖水)所形成的生物膜/生物污染也进行了对比研究。研究表明,自来水过滤系统产生了比湖水更严重的膜污染,而且多糖和eDNA的含量更高。其生物膜形态致密,但是湖水形成的生物膜是多孔、类似蜘蛛网状的结构,猜测可能与生物膜中的细菌有关。16S rRNA测序结果表明,Xanthobacter在自来水形成的生物膜中占据优势地位。此外,研究发现膜的亲、疏水性对膜污染特性和微生物群落的影响较小。本研究揭示了耐氯细菌在膜污染形成中的重要作用,更深入地认识了膜污染,可为寻求有效的膜污染控制方法提供帮助。

关键词: 膜污染     生物膜     GDM过滤技术     超滤     耐氯细菌     亲水性    

Sea salt bittern-driven forward osmosis for nutrient recovery from black water: A dual waste-to-resourceinnovation via the osmotic membrane process

Wenchao Xue, May Zaw, Xiaochan An, Yunxia Hu, Allan Sriratana Tabucanon

《环境科学与工程前沿(英文)》 2020年 第14卷 第2期 doi: 10.1007/s11783-019-1211-7

摘要: • A dual “waste-to-resource” application of FO was proposed. • Performance of sea salt bittern as an economic FO draw solution was evaluated. • High quality struvite recovery from black water using FO was demonstrated. • Feed pH is a key factor to control the form of recovered phosphorous. A dual “waste-to-resource” innovation in nutrient enrichment and recovery from domestic black water using a sea salt bittern (SSB)-driven forward osmosis (FO) process is proposed and demonstrated. The performance of SSB as a “waste-to-resource” draw solution for FO was first evaluated. A synthetic SSB-driven FO provided a water flux of 25.67±3.36 L/m2⋅h, which was 1.5‒1.7 times compared with synthetic seawater, 1 M NaCl, and 1 M MgCl2. Slightly compromised performance regarding reverse solute selectivity was observed. In compensation, the enhanced reverse diffusion of Mg2+ suggested superior potential in terms of recovering nutrients in the form of struvite precipitation. The nutrient enrichment was performed using both the pre-filtered influent and effluent of a domestic septic tank. Over 80% of phosphate-P recovery was achieved from both low- and high-strength black water at a feed volume reduction up to 80%‒90%. With an elevated feed pH (~9), approximately 60%‒85% enriched phosphate-P was able to be recovered in the form of precipitated stuvite. Whereas the enrichment performance of total Kjeldahl nitrogen (TKN) largely differed depending on the strength of black water. Improved concentration factor (i.e., 3-folds) and retention (>60%) of TKN was obtained in the high-nutrient-strength black water at a feed volume reduction of 80%, in comparison with a weak TKN enrichment observed in low-strength black water. The results suggested a good potential for nutrient recovery based on this dual “waste-to-resource” FO system with proper management of membrane cleaning.

关键词: Forward osmosis     Sea salt bittern     Black water     Nutrient recovery     pH    

计算流体力学在水处理膜过程中的应用

张雅琴,张林,侯立安

《中国工程科学》 2014年 第16卷 第7期   页码 47-52

摘要:

本文介绍了计算流体力学(CFD)在膜分离过程模拟中的基本原理,对CFD在压力膜驱动过程组件设计、传质和膜污染过程研究方面的应用和CFD在具有相变膜过程(渗透汽化、膜蒸馏)以及其他膜过程中的应用分别进行了综述,最后对CFD在膜分离技术研究中的应用前景进行了展望。

关键词: 计算流体力学     膜分离     压力驱动     渗透汽化     膜蒸馏    

High-gravity intensified iron-carbon micro-electrolysis for degradation of dinitrotoluene

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1595-1605 doi: 10.1007/s11705-022-2204-9

摘要: The application of iron–carbon (Fe–C) micro-electrolysis to wastewater treatment is limited by the passivation potential of the Fe–C packing. In order to address this problem, high-gravity intensified Fe–C micro-electrolysis was proposed in this study for degradation of dinitrotoluene wastewater in a rotating packed bed (RPB) using commercial Fe–C particles as the packing. The effects of reaction time, high-gravity factor, liquid flow rate and initial solution pH were investigated. The degradation intermediates were determined by gas chromatography-mass spectrometry, and the possible degradation pathways of nitro compounds by Fe–C micro-electrolysis in RPB were also proposed. It is found that under optimal conditions, the removal rate of nitro compounds reaches 68.4% at 100 min. The removal rate is maintained at approximately 68% after 4 cycles in RPB, but it is decreased substantially from 57.9% to 36.8% in a stirred tank reactor. This is because RPB can increase the specific surface area and the renewal of the liquid–solid interface, and as a result the degradation efficiency of Fe–C micro-electrolysis is improved and the active sites on the Fe–C surface can be regenerated for continuous use. In conclusion, high-gravity intensified Fe–C micro-electrolysis can weaken the passivation of Fe–C particles and extend their service life.

关键词: high-gravity technology     rotating packed bed     Fe–C micro-electrolysis     dinitrotoluene wastewater     active sites    

卫星重力梯度数据用于精化地球重力场的研究

宁津生,罗志才,陈永奇

《中国工程科学》 2002年 第4卷 第7期   页码 23-28

摘要:

确定厘米级大地水准面和发展超高阶地球重力场模型是现代物理大地测量的主要科学目标之一。卫星重力梯度测量的实现将为这一目标做出重大贡献。文章着重评述这一领域的研究进展,并讨论利用卫星重力梯度数据精化地球重力场的若干理论和方法问题。

关键词: 卫星重力梯度测量     卫星重力梯度边值问题     地球重力场模型     大地水准面    

Stability analysis on Tingzikou gravity dam along deep-seated weak planes during earthquake

Weiping HE, Yunlong HE

《结构与土木工程前沿(英文)》 2012年 第6卷 第1期   页码 69-75 doi: 10.1007/s11709-012-0146-x

摘要: The stability of a gravity dam against sliding along deep-seated weak planes is a universal and important problem encountered in the construction of dams. There is no recommended method for stability analysis of the dam on deep-seated weak planes under earthquake condition in Chinese design codes. Taking Tingzikou dam as an example, the research in this paper is focused on searching a proper way to evaluate the seismic safety of the dam against sliding along deep-seated weak planes and the probable failure modes of dam on deep-seated weak planes during earthquake. It is concluded that there are two probable failure modes of the dam along the main weak geological planes in the foundation. In the first mode, the concrete tooth under the dam will be cut and then the dam together with part foundation will slide along the muddy layer; in the second mode, the dam together with part foundation will slide along the path consist of the weak rock layer under the tooth and the muddy layer downstream the tooth. While there is no geological structure planes to form the second slip surface, the intersection of the main and the second slip surface is 40 to 80 m downstream from dam toe, and the angle between the second slip surface and the horizontal plane probably be 25 to 45 degrees.

关键词: gravity dam     deep-seated weak planes     stability against sliding     earthquake    

A comprehensive simulation approach for pollutant bio-transformation in the gravity sewer

Nan Zhao, Huu Hao Ngo, Yuyou Li, Xiaochang Wang, Lei Yang, Pengkang Jin, Guangxi Sun

《环境科学与工程前沿(英文)》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1144-1

摘要:

A comprehensive pollutant transformation model for sewer systems is established.

The model comprises fermentation, sulfate reduction and ammonification processes.

Biochemical reactions related to distinct carbon sources are depicted in the model.

Pollutant transformation is attributed to different biochemical reaction processes.

关键词: Gravity sewer     Modeling     Pollutant transformation     Biochemical reaction process    

Evaluation of seismic reliability of gravity dam-reservoir-inhomogeneous foundation coupled system

Hamid Taghavi GANJI, Mohammad ALEMBAGHERI, Mohammad Houshmand KHANEGHAHI

《结构与土木工程前沿(英文)》 2019年 第13卷 第3期   页码 701-715 doi: 10.1007/s11709-018-0507-1

摘要: The seismic performance of gravity dam-reservoir-foundation coupled system is investigated utilizing probabilistic approach. In this research, the uncertainties associated with modeling parameters are incorporated in nonlinear response history simulations to realistically quantify their effects on the seismic performance of the system. The methodology is applied to Pine Flat gravity dam and the foundation is considered to be inhomogeneous assuming a constant spatial geometry but with various rock material properties. The sources of uncertainty are taken into account in the reliability analysis using Latin Hypercube Sampling procedure. The effects of the deconvolution process, number of samples, and foundation inhomogeneity are investigated.

关键词: gravity dams     dam-reservoir-foundation interaction     seismic reliability     inhomogeneous foundation     earthquake deconvolution    

State-of-the-art on theories and applications of cable-driven parallel robots

《机械工程前沿(英文)》 2022年 第17卷 第3期 doi: 10.1007/s11465-022-0693-3

摘要: Cable-driven parallel robot (CDPR) is a type of high-performance robot that integrates cable-driven kinematic chains and parallel mechanism theory. It inherits the high dynamics and heavy load capacities of the parallel mechanism and significantly improves the workspace, cost and energy efficiency simultaneously. As a result, CDPRs have had irreplaceable roles in industrial and technological fields, such as astronomy, aerospace, logistics, simulators, and rehabilitation. CDPRs follow the cutting-edge trend of rigid–flexible fusion, reflect advanced lightweight design concepts, and have become a frontier topic in robotics research. This paper summarizes the kernel theories and developments of CDPRs, covering configuration design, cable-force distribution, workspace and stiffness, performance evaluation, optimization, and motion control. Kinematic modeling, workspace analysis, and cable-force solution are illustrated. Stiffness and dynamic modeling methods are discussed. To further promote the development, researchers should strengthen the investigation in configuration innovation, rapid calculation of workspace, performance evaluation, stiffness control, and rigid–flexible coupling dynamics. In addition, engineering problems such as cable materials, reliability design, and a unified control framework require attention.

关键词: cable-driven parallel robot     kinematics     optimization     dynamics     control    

mechanism of nitrobenzene degradation by hydroxyl radicals-based ozonation process enhanced by high gravity

Weizhou Jiao, Shengjuan Shao, Peizhen Yang, Kechang Gao, Youzhi Liu

《化学科学与工程前沿(英文)》 2021年 第15卷 第5期   页码 1197-1205 doi: 10.1007/s11705-020-1998-6

摘要: This study investigated the indirect oxidation of nitrobenzene (NB) by hydroxyl radicals (·OH) in a rotating packed bed (RPB) using competitive kinetics method with -nitrochlorobenzene as a reference compound. The rate constants of NB with ·OH are calculated to be between (1.465±0.113) × 10 L/(mol·s) and (2.497±0.192) × 10 L/(mol·s). The experimental data are fitted by the modified Arrhenius equation, where the activation energy is 4877.74 J/mol, the order of NB concentration, rotation speed, and initial pH is 0.2425, 0.1400 and 0.0167, respectively. The ozonation process of NB could be enhanced by RPB, which is especially effective for highly concentrated NB-containing wastewater under alkaline conditions. The high gravity technology can accelerate ozone mass transfer and self-decomposition of ozone to produce more ·OH, resulting in an increase in the indirect oxidation rate of NB by ·OH and consequently effective degradation of NB in wastewater.

关键词: high gravity technology     hydroxyl radicals     nitrobenzene     reaction kinetics    

Hazard potential of zones of weakness in gravity dams under impact loading conditions

Herbert LINSBAUER

《结构与土木工程前沿(英文)》 2011年 第5卷 第1期   页码 90-97 doi: 10.1007/s11709-010-0008-3

摘要: Dam constructions worldwide are designed and constructed in view of the strictest safety aspects for all static and dynamic load cases. As experience shows, however, formation of cracks in the “homogeneos concrete” as well as unsatisfactory compound behavior of lift joints are not to be excluded. These zones of weakness especially on the upstream side of the dam— exposed to high water pressure (static and dynamic)— represent an increased risk of safety. The main investigation, apart from the computation of the dynamic effects on the dam as a global structure, focuses on the stability analysis of a pressure-water filled crack configuration subjected to “dynamic loading” in the form of seismic action on the dam-reservoir-system and alternatively by “impact spot-loading” within sectors of the reservoir. A fracture mechanics based analysis shows an excessive potential of damage for the afflicted structure.

关键词: dam-reservoir     earthquake     impact     cracking     fracture mechanics    

Earthquake analysis of arch and gravity dams including the effects of foundation inhomogeneity

LIN Gao, DU Jianguo, HU Zhiqiang

《结构与土木工程前沿(英文)》 2007年 第1卷 第1期   页码 41-50 doi: 10.1007/s11709-007-0004-4

摘要: Dam-foundation interaction plays an important role in the design of earthquake-resistant concrete arch and gravity dams. Geological conditions of the dam canyon are usually very complicated; however, in the literature, the damfoundation interaction analysis is often carried out based on the premise of a homogeneous unbounded foundation. In this paper, the effect of foundation inhomogeneity on the seismic response of arch and gravity dams was studied by means of scaled boundary finite element method (SBFEM). In order to satisfy the similarity requirement of SBFEM and simplify the computational effort, a subdomain approach and a conical representation of an unbounded foundation were proposed. The way of partitioning the domain and the selection of open angle and bottom radius of the cone model on the accuracy of the result were examined. Numerical examples show that the proposed approach is rational and efficient. Cases of foundation inhomogeneity with stiffness varying in accordance with an exponential function along the radial direction, and cases of foundation inhomogeneity with stiffness discontinuity and with weak interlayer strata on the earthquake response of concrete arch dams as well as gravity dams were analyzed. It was found that a homogeneous idealization of the unbounded foundation may sometimes greatly underestimate the maximum earthquake stress response of the dam. Therefore, taking into account the effect of foundation inhomogeneity for the earthquake safety assessment of concrete arch and gravity dams has great significance.

关键词: selection     interlayer     damfoundation interaction     Geological     computational    

Function-oriented optimization design method for underactuated tendon-driven humanoid prosthetic hand

《机械工程前沿(英文)》 2022年 第17卷 第3期 doi: 10.1007/s11465-022-0696-0

摘要: The loss of hand functions in upper limb amputees severely restricts their mobility in daily life. Wearing a humanoid prosthetic hand would be an effective way of restoring lost hand functions. In a prosthetic hand design, replicating the natural and dexterous grasping functions with a few actuators remains a big challenge. In this study, a function-oriented optimization design (FOD) method is proposed for the design of a tendon-driven humanoid prosthetic hand. An optimization function of different functional conditions of full-phalanx contact, total contact force, and force isotropy was constructed based on the kinetostatic model of a prosthetic finger for the evaluation of grasping performance. Using a genetic algorithm, the optimal geometric parameters of the prosthetic finger could be determined for specific functional requirements. Optimal results reveal that the structure of the prosthetic finger is significantly different when designed for different functional requirements and grasping target sizes. A prosthetic finger was fabricated and tested with grasping experiments. The mean absolute percentage error between the theoretical value and the experimental result is less than 10%, demonstrating that the kinetostatic model of the prosthetic finger is effective and makes the FOD method possible. This study suggests that the FOD method enables the systematic evaluation of grasping performance for prosthetic hands in the design stage, which could improve the design efficiency and help prosthetic hands meet the design requirements.

关键词: function-oriented     tendon driven     prosthetic hand     optimization     humanoid     underactuated    

标题 作者 时间 类型 操作

uncoupler, 3,3′,4′,5-tetrachlorosalicylanilide addition for sludge reduction and fouling control in a gravity-drivenmembrane bioreactor

An Ding, Yingxue Zhao, Huu Hao Ngo, Langming Bai, Guibai Li, Heng Liang, Nanqi Ren, Jun Nan

期刊论文

Dynamic analysis of free-surface thin film flows driven by gravity over undulated substrate

Zhaomiao LIU, Xin LIU, Guobin WANG, Hong LIAO,

期刊论文

氯化水与地表水导致的膜污染对比解析——生物污染特性和微生物探究

张莉, 徐磊, Nigel Graham, 俞文正

期刊论文

Sea salt bittern-driven forward osmosis for nutrient recovery from black water: A dual waste-to-resourceinnovation via the osmotic membrane process

Wenchao Xue, May Zaw, Xiaochan An, Yunxia Hu, Allan Sriratana Tabucanon

期刊论文

计算流体力学在水处理膜过程中的应用

张雅琴,张林,侯立安

期刊论文

High-gravity intensified iron-carbon micro-electrolysis for degradation of dinitrotoluene

期刊论文

卫星重力梯度数据用于精化地球重力场的研究

宁津生,罗志才,陈永奇

期刊论文

Stability analysis on Tingzikou gravity dam along deep-seated weak planes during earthquake

Weiping HE, Yunlong HE

期刊论文

A comprehensive simulation approach for pollutant bio-transformation in the gravity sewer

Nan Zhao, Huu Hao Ngo, Yuyou Li, Xiaochang Wang, Lei Yang, Pengkang Jin, Guangxi Sun

期刊论文

Evaluation of seismic reliability of gravity dam-reservoir-inhomogeneous foundation coupled system

Hamid Taghavi GANJI, Mohammad ALEMBAGHERI, Mohammad Houshmand KHANEGHAHI

期刊论文

State-of-the-art on theories and applications of cable-driven parallel robots

期刊论文

mechanism of nitrobenzene degradation by hydroxyl radicals-based ozonation process enhanced by high gravity

Weizhou Jiao, Shengjuan Shao, Peizhen Yang, Kechang Gao, Youzhi Liu

期刊论文

Hazard potential of zones of weakness in gravity dams under impact loading conditions

Herbert LINSBAUER

期刊论文

Earthquake analysis of arch and gravity dams including the effects of foundation inhomogeneity

LIN Gao, DU Jianguo, HU Zhiqiang

期刊论文

Function-oriented optimization design method for underactuated tendon-driven humanoid prosthetic hand

期刊论文